3.27.2010

Calculating H+ and OH- Concentration in solution

For strong acids and strong bases, the calculation of [H+ ] and [OH-] depends on the valence and concentration of the strong acid or strong base solution. Look at the following formula.

[H+] = M x acid valence

[OH-] = M x base valence

For weak acid and weak bases, the formula to calculate [H+] and [OH-] of weak acids and weak bases is gained from the equation of acid ionization constant (Ka) and base ionization constant (Kb)

[H+] =

[OH-] =

Relation concentration of H+ and OH- with ionization degree (α) can be shown with the equation as follows:

[H+] = M x α

[OH-] = M x α    

Example

Calculate the concentration of OH- in the solution if 8 gr NaOH (Mr=40) dissolved into water until 20 liter!

Mol NaOH= 8gr/40

        = 0,2 mol

M NaOH= 0,2 mol/20 L=0,01 M

[OH-]=10-2